DTIC ADA1046583: Mechanism of Monuron Accelerated Dicyandiamide pdf

DTIC ADA1046583: Mechanism of Monuron Accelerated Dicyandiamide

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A very interesting and practical property of trisubstituted ureas such as Monuron, is the ability of this class of aryl ureas to accelerate the dicyandiamide (Dicy) cure of epoxy resins. Earlier workers had proposed that the in situ formation of dimethylamine from Monuron was an important factor in explaining the mechanism of the Monuron-accelerated dicyandiamide cure of epoxy resins. The main source of dimethylamine did not appear to us to be that which had been previously described. We have found that the amine is generated by a cyclocondensation reaction between the aryl urea and the resin to form a 2- oxazolidone. During this study, it was found that the effectiveness with which dimethylamine activates Dicy, especially when compared to other materials such as trimethylamine, made this amine unique. It is postulated that dimethylamine has a strong proclivity to remove a proton from Dicy, thereby creating a highly active nucleophilic species.

This enhancement of the nucleophilic nature of the hardening agent (DICY) would account for the increased reactivity of Dicy toward epoxy resins

• Creator/s: Defense Technical Information Center
• Date: 7/1/1981
• Year: 1981
• Book Topics/Themes: DTIC Archive, LaLiberte, Bernard R, ARMY MATERIALS AND MECHANICS RESEARCH CENTER WATERTOWN MA, *CURING, *EPOXY COMPOUNDS, *EPOXY RESINS, ADDITIVES, AMINES, ARYL RADICALS, CYANAMIDES, HARDENING, METHYLAMINE, OXAZINES, REACTION TIME, UREA

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