DTIC ADA192150: Electrochemistry and Spectroelectrochemistry of Polynuclear pdf

DTIC ADA192150: Electrochemistry and Spectroelectrochemistry of Polynuclear

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The electrochemistry and spectroelectrochemistry of mononuclear, binuclear and tetranuclear zinc neopentoxy-substituted phthalocyanines are presented. The binuclear and tetranuclear species show two oxidation waves to the radical cation indicating the existence of stable mixed valence, half-oxidized species. The electronic spectra of the half- and fully oxidized species are presented and discussed. Nernstian analysis shows that pairs of phthalocyanine oxidation pathway. Keywords: Phthalocyanine, Electrochemistry, Mixed valence, Spectro-electrochemistry

• Creator/s: Defense Technical Information Center
• Date: 2/25/1988
• Year: 1988
• Book Topics/Themes: DTIC Archive, Manivannan, V, YORK UNIV DOWNSVIEW (ONTARIO) DEPT OF CHEMISTRY, *ELECTROCHEMISTRY, *PHTHALOCYANINES, *SPECTRA, *ZINC COMPOUNDS, CATIONS, ELECTRONICS, MIXING, OXIDATION, STABILITY, VALENCE

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