DTIC ADA631574: Roaming Reactions and Roaming Mediated pdf

DTIC ADA631574: Roaming Reactions and Roaming Mediated

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Description of the Book:

In the course of this project, roaming reactions and roaming-mediated isomerization were studied in a range of nitro compounds. To this end, infrared multi photon dissociation was coupled to state-resolved velocity map imaging for the first time. Systems studied in detail included nitromethane, nitroethane, 1-nitropropane and nitrobutane, as well as the corresponding nitrites. In addition, these same techniques were applied to vinyl chloride dissociation, where state-resolved imaging clearly showed the ground state dissociation at threshold proceeds by 3- center elimination to give the elusive vinylidene reaction intermediate as a product

• Creator/s: Defense Technical Information Center
• Date: 12/2/2015
• Year: 2015
• Book Topics/Themes: DTIC Archive, , WAYNE STATE UNIV DETROIT MI, *ENERGETIC PROPERTIES, *ISOMERIZATION, CHLORIDES, COUPLING(INTERACTION), DECOMPOSITION, DISSOCIATION, ELIMINATION, GROUND STATE, IMAGES, INFRARED RADIATION, MAPS, MATERIALS, PHOTONS, RESPONSE, VELOCITY, VINYL PLASTICS

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